Product Code Database
The glass battery is a type of solid-state battery. It uses a glass electrolyte and lithium or sodium metal electrodes.
The paper describing the battery was published in Energy & Environmental Science in December 2016; a number of follow-up works have also been published since. Hydro-Québec is researching the battery for possible production.
Goodenough responded to the skepticism, stating: "The answer is that if the lithium plated on the cathode current collector is thin enough for its reaction with the current collector to have its Fermi energy lowered to that of the current collector, the Fermi energy of the lithium anode is higher than that of the thin lithium plated on the cathode current collector." Goodenough went on to say in a later interview with Slashdot that the lithium plated on the cathode is on the "order of a micron thick".
Goodenough's response has drawn further skepticism from Daniel Steingart and also Matthew Lacey of Uppsala University, who point out that this underpotential deposition effect is only known for extremely thin layers (monolayers) of materials. Lacey also notes that the original publication does not mention a limit to the thickness of the lithium plated on the cathode, but instead states the opposite: that the capacity of the cell is "determined by the amount of alkali metal used as the anode".
The publication states the battery operates during discharge by stripping the alkali metal from the anode and re-depositing it at the cathode, with the battery voltage determined by the redox active component and the Battery capacity of the battery determined by the amount of the alkali metal anode. This operating mechanism is radically different from the insertion (intercalation) mechanism of most conventional Li-ion battery materials.
In 2018, a new version was described by most of the same authors in the Journal of the American Chemical Society, in which the cathode is coated with a special plasticiser solution to avoid interface cracking as different materials expand at different rates. Braga says the new battery has twice the energy density of conventional lithium-ion batteries, and can be recharged 23,000 times. Critics pointed out several extraordinary claims in the paper, such as a record-high relative dielectric constant; perhaps higher than any material recorded, and a raise in the capacitance of the battery over many charge cycles, rather than a decrease as is usually the case with all other battery technologies. The paper was also not clear if the battery could hold its charge after it is unplugged, which would clarify whether it is really a new battery technology, or simply a capacitor. Braga responded to critics, saying "Data is data, and we have similar data from many different cells, in four different instruments, different labs, glove box. And at the end of the day, the LEDs are lit for days with a very small amount of active material after having cycled for more than 23,000 times".
The authors claim the battery has a much shorter charging time than Li-ion batteries—in minutes rather than hours. The authors also state they tested the stability of the alkali metal/electrolyte interface over 1,200 charge cycles with low cell resistance; the specification for Li-ion batteries is usually less than a thousand.Tim De Chant, "Super-Safe Glass Battery Charges in Minutes, Not Hours", NovaNext, 17 March 2017.Mark Anderson, "Will a New Glass Battery Accelerate the End of Oil?", IEEE Spectrum, 3 March 2017
|
|
